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Anthocyanins/chitosan films doped by nano zinc oxide for active and intelligent packaging: comparison of anthocyanins source from purple tomato or black wolfberry

《化学科学与工程前沿(英文)》 2023年 第17卷 第6期   页码 704-715 doi: 10.1007/s11705-022-2270-z

摘要: The multifunctional films was prepared by blending chitosan and nano-ZnO with purple tomato anthocyanins or black wolfberry anthocyanins. The properties of films functioned by anthocyanins source and nano-ZnO content were studied. It was found purple tomato anthocyanins showed more significant color change against pH than black wolfberry anthocyanins. The nano-ZnO were widely dispersed in matrix and enhanced the compatibility of anthocyanins with chitosan. However, the anthocyanins source influenced the properties of the films more slightly than nano-ZnO addition. The tensile strength, antioxidant and antibacterial effects of the chitosan films dramatically increased after cooperated by nano-ZnO and anthocyanins, which also enhanced with increase of nano-ZnO content, whereas the elongation at break of the composite films decreased. Especially, the anthocyanin and nano-ZnO promoted the antibacterial activity of films synergistically. Composite films made from black wolfberry anthocyanins exhibited higher mechanical performance than those made from purple tomato anthocyanins but weaker antibacterial effects. The purple tomato anthocyanins/chitosan and nano-ZnO/purple tomato anthocyanins/chitosan films effectively reflected pork spoilage, changing their colors from dark green to brown, indicating the potential for applications in active and intelligent food packaging.

关键词: bio-based     multifunction     colorimetric indicator     active and intelligent packaging    

A cellphone-based colorimetric multi-channel sensor for water environmental monitoring

《环境科学与工程前沿(英文)》 2022年 第16卷 第12期 doi: 10.1007/s11783-022-1590-z

摘要:

● A cellphone-based colorimetric multi-channel sensor for in-field detection.

关键词: Colorimetric analysis     Multi-channel sensor     Cellphone     Water quality indexes     Environmental monitoring    

Label-free colorimetric nanosensor with improved sensitivity for Pb

Abdul Ghaffar Memon, Xiaohong Zhou, Yunpeng Xing, Ruoyu Wang, Lanhua Liu, Mohsin Khan, Miao He

《环境科学与工程前沿(英文)》 2019年 第13卷 第1期 doi: 10.1007/s11783-019-1094-7

摘要:

• Unmodified-AuNP based, colorimetric nanosensor was constructed for Pb2+ detection.

• 5-nucleotide truncation in DNAzyme made complete substrate detachment upon Pb2+.

• Ultrasensitive and selective detection of Lead (II) was achieved with 0.2×10-9 mol/L LOD.

关键词: Colorimetric nanosensor     Truncated 8–17 DNAzyme     Pb2+ detection     Unmodified AuNPs    

Midline2 is overexpressed and a prognostic indicator in human breast cancer and promotes breast cancer

《医学前沿(英文)》 2021年 第15卷 第6期   页码 942-942 doi: 10.1007/s11684-021-0876-z

Biomineralization-inspired copper-cystine nanoleaves capable of laccase-like catalysis for the colorimetric

Miao Guan, Mengfan Wang, Wei Qi, Rongxin Su, Zhimin He

《化学科学与工程前沿(英文)》 2021年 第15卷 第2期   页码 310-318 doi: 10.1007/s11705-020-1940-y

摘要: Recently, many efforts have been dedicated to creating enzyme-mimicking catalysts to replace natural enzymes in practical fields. Inspired by the pathological biomineralization behaviour of L-cystine, in this study, we constructed a laccase-like catalyst through the co-assembly of L-cystine with Cu ions. Structural analysis revealed that the formed catalytic Cu-cystine nanoleaves (Cu-Cys NLs) possess a Cu(I)-Cu(II) electron transfer system similar to that in natural laccase. Reaction kinetic studies demonstrated that the catalyst follows the typical Michaelis-Menten model. Compared with natural laccase, the Cu-Cys NLs exhibit superior stability during long-term incubation under extreme pH, high-temperature or high-salt conditions. Remarkably, the Cu-Cys NLs could be easily recovered and still maintained 76% of their activity after 8 cycles. Finally, this laccase mimic was employed to develop a colorimetric method for epinephrine detection, which achieved a wider linear range (9–455 μmol·L ) and lower limit of detection (2.7 μmol·L ). The Cu-Cys NLs also displayed excellent specificity and sensitivity towards epinephrine in a test based on urine samples.

关键词: biomineralization     laccase     L-cystine     colorimetric detection     enzyme mimic    

Screening of indicator pharmaceuticals and personal care products in landfill leachates: a case study

《环境科学与工程前沿(英文)》 2023年 第17卷 第9期 doi: 10.1007/s11783-023-1716-y

摘要:

● A systematic framework was developed to identify i-PPCPs for landfill leachate.

关键词: Landfill leachates     PPCPs     Indicator     Screening criteria     Source-specificity    

Investigating the role of exiting vehicles and turn indicator usage in gap acceptance at single-lane

Nathan P. BELZ

《结构与土木工程前沿(英文)》 2017年 第11卷 第1期   页码 8-16 doi: 10.1007/s11709-016-0365-7

摘要: Roundabouts are becoming a preferred form of intersection control type due to their safety and capacity benefits. Yield control at roundabout entries inherently reduces fuel consumption and emissions when compared to other conventional intersection types. However, these benefits can be limited by poor driver behavior and judgment when entering the roundabout. This research addresses the nature of gap distributions and use of turn indicators by exiting vehicles at three single-lane roundabouts in Vermont, New York, and Alaska. Presented here is a comparison of vehicle headways measured at two different locations in each roundabout. Rejected headways are analyzed in the context of priority abstaining events when entering drivers yield to vehicles exiting on the same leg of the roundabout suggesting that “true” critical gaps are being overestimated. Results indicate that exiting vehicles, particularly those that do not use their turn indicators when departing from the major-stream of traffic have an influence on the entry decision of drivers on the same approach. This behavior is of particular concern for intersection efficiency (i.e., delay) and sustainability (i.e., excess fuel consumption and emissions). Results prompt the consideration of more consistent guidance on and enforcement of turn indicator use during roundabout negotiations.

关键词: roundabouts     exiting vehicles     turn indicator use     headways    

Modeling effects of a tidal barrage on water quality indicator distribution in the Severn Estuary

Guanghai GAO, Roger A. FALCONER, Binliang LIN

《环境科学与工程前沿(英文)》 2013年 第7卷 第2期   页码 211-218 doi: 10.1007/s11783-012-0464-1

摘要: In this study, emphasis has focused on assessing the potential hydro-environmental impacts of a barrage across the Severn Estuary, with a numerical model being developed and applied to the estuary to assess the impacts of proposed Severn Barrage on the hydrodynamic, sediment transport and faecal indicator organism distribution within the estuary. The results show that the Severn Barrage has the potential to reduce the tidal currents in a highly dynamic estuary. This leads to the reduction of suspended sediment concentrations, which in turn affects the bacterial transport processes which is highly related to the sediment transport processes.

关键词: water quality indicator     Severn Estuary     numerical model     tidal energy    

A novel flavonol-based colorimetric and turn-on fluorescent probe for rapid determination of hydrazine

《化学科学与工程前沿(英文)》 2023年 第17卷 第1期   页码 24-33 doi: 10.1007/s11705-022-2171-1

摘要: Hydrazine is extremely toxic and causes severe harm to human body. Herein, a novel fluorescent probe 4-oxo-2-styryl-4H-chromen-3-yl thiophene-2-carboxylate (FHT) was synthesized for detecting hydrazine by using natural cinnamaldehyde as starting material. This probe exhibited significantly enhanced fluorescence response towards hydrazine over various common metal ions, anions, and amine compounds. The detection limit of probe FHT for hydrazine was as low as 0.14 μmol·L–1, significantly lower than that of the threshold value of 0.312 μmol·L–1, imposed by the Environmental Protection Agency. Moreover, the proposed probe was able to detect hydrazine within wide pH (5–10) and linear detection ranges (0–110 μmol·L–1). This probe was employed for determining trace hydrazine in different environmental water samples. The probe FHT-loaded filter paper strips were able to conveniently detect hydrazine of low concentration through distinct naked-eye and fluorescent color changes. Importantly, the probe FHT with low cytotoxicity was successfully applied to visualize hydrazine in living Hela cells and zebrafish.

关键词: cinnamaldehyde     3-hydroxychromone derivative     hydrazine     fluorescent probe    

Water environment security indicator system for urban water management

Tian HAO, Pengfei DU, Yun GAO

《环境科学与工程前沿(英文)》 2012年 第6卷 第5期   页码 678-691 doi: 10.1007/s11783-012-0450-7

摘要: Water environment security (WES) is defined in terms of three aspects: first, that it meets basic demands due to industrial and domestic usage; second, that it protects public health from acute and chronic threats; and third, that measures are adopted to ensure sustainable ecological functioning of freshwater resources. Limitations associated with current water environment security indicators in China — including inefficiency in terms of environmental monitoring, inappropriate indicators and parameters that do not take sufficient account of local water characteristics, and a lack of management targets — leads to a failure of effective water management. To achieve better water environment management, a systematic approach, encompassing several steps including establish ideal indicator system and narrow down the scope, screen priority pollutants, identify local characteristics and organize discussion workshop, should be followed to establish a comprehensive water environment indicator system. A case study in Suzhou is included to demonstrate the detailed operational procedures used to assess the risks associated with poor management practices relating to water environment security as well as design an appropriate water environment security indicator system.

关键词: water environment security     supervision and management     monitoring parameter     indicator system     Suzhou    

China’s Agriculture Green Development: from Concept to Actions

《农业科学与工程前沿(英文)》 doi: 10.15302/J-FASE-2023512

摘要:

● A target-threshold indicator evaluation system is proposed to measure China’s agriculture transformation.

关键词: agricultural transformation     Agriculture Green Development     historical trend     indicator system     theoretical conception    

A simple, azulene-based colorimetric probe for the detection of nitrite in water

Lloyd C. Murfin, Carlos M. López-Alled, Adam C. Sedgwick, Jannis Wenk, Tony D. James, Simon E. Lewis

《化学科学与工程前沿(英文)》 2020年 第14卷 第1期   页码 90-96 doi: 10.1007/s11705-019-1790-7

摘要: We describe the synthesis and evaluation of an azulene-based chemodosimeter for nitrite. The probe was found to undergo two distinct color changes upon introduction aqueous nitrite ion. A near-instant formation of a grey color provides a qualitative indication of the presence of nitrite, followed by the formation of a deep-yellow/orange color, the endpoint from which quantitative data can be derived. The azulene probe exhibits 1:1 stoichiometry of reaction with nitrite in water, and is selective for nitrite over other anions. The azulene probe was applied to determine nitrite content in cured meat, and compared with the British Standard testing procedure (Griess test). The value obtained from the azulene-based probe agreed closely with the standard test. Our procedure only requires the preparation of one standard solution, instead of the three required for the standard Griess test.

关键词: azulene     nitrite     diazoquinone    

Midline2 is overexpressed and a prognostic indicator in human breast cancer and promotes breast cancer

null

《医学前沿(英文)》 2016年 第10卷 第1期   页码 41-51 doi: 10.1007/s11684-016-0429-z

摘要:

Midline2 (MID2) is an ubiquitin-conjugating E2 enzyme linked to tumor progression and a novel interacting partner of breast cancer 1, early-onset (BRCA1). However, the role of MID2 in breast cancer remains unknown. This study investigated the expression, prognostic value, and role of MID2 in breast cancer. The expression of MID2 mRNA and protein was significantly upregulated in breast cancer tissue and established cell lines compared with that in normal breast epithelial cells and paired adjacent non-tumor tissue (P<0.001). Immunohistochemical analysis demonstrated that MID2 was overexpressed in 272 of 284 (95.8%) paraffin-embedded, archived breast cancer tissue. Moreover, MID2 expression increased with advanced clinical stage (P<0.001). High MID2 expression was significantly associated with advanced clinical stages and T, N, and M staging (all P<0.05). Univariate and multivariate analyses indicated that high MID2 expression was an independent prognostic factor for poor overall survival in the entire cohort (93.73 vs. 172.1 months; P<0.001, log-rank test) and in subgroups with stages Tis+ I+ II and III+ IV. Furthermore, 3-(4,5-dimethyl-2-thiazolyl)-2,5-diphenyl-2H-tetrazolium bromide colony formation, and anchorage-independent growth ability assays were conducted. Results showed that siRNA silencing of MID2 expression significantly reduced MCF-7 and MDA-MB-231 cell proliferation in vitro and blocked the growth of MDA-MB-231 cell xenograft tumors in vivo (P<0.05). This study indicated that MID2 may be a novel prognostic marker and interventional target in breast cancer.

关键词: breast cancer     MID2     proliferation     overall survival     xenograft    

A review of measurement methods for peracetic acid (PAA)

Chen Cheng, Haodong Li, Jinling Wang, Hualin Wang, Xuejing Yang

《环境科学与工程前沿(英文)》 2020年 第14卷 第5期 doi: 10.1007/s11783-020-1266-5

摘要: Abstract • Physical and chemical properties and application of peracetic acid solution. • Determination method of high concentration peracetic acid. • Determination method of residual peracetic acid (low concentration). Peroxyacetic acid has been widely used in food, medical, and synthetic chemical fields for the past several decades. Recently, peroxyacetic acid has gradually become an effective alternative disinfectant in wastewater disinfection and has strong redox capacity for removing micro-pollutants from drinking water. However, commercial peroxyacetic acid solutions are primarily multi-component mixtures of peroxyacetic acid, acetic acid, hydrogen peroxide, and water. During the process of water treatment, peroxyacetic acid and hydrogen peroxide (H2O2) often coexist, which limits further investigation on the properties of peroxyacetic acid. Therefore, analytical methods need to achieve a certain level of selectivity, particularly when peroxyacetic acid and hydrogen peroxide coexist. This review summarizes the measurement and detection methods of peroxyacetic acid, comparing the principle, adaptability, and relative merits of these methods.

关键词: Peroxyacetic acid     Measurement methods     Titration     Colorimetric     Chromatography     NMR    

Nonlinear dynamic behavior of rotating blade with breathing crack

Laihao YANG, Zhu MAO, Shuming WU, Xuefeng CHEN, Ruqiang YAN

《机械工程前沿(英文)》 2021年 第16卷 第1期   页码 196-220 doi: 10.1007/s11465-020-0609-z

摘要: This study aims at investigating the nonlinear dynamic behavior of rotating blade with transverse crack. A novel nonlinear rotating cracked blade model (NRCBM), which contains the spinning softening, centrifugal stiffening, Coriolis force, and crack closing effects, is developed based on continuous beam theory and strain energy release rate method. The rotating blade is considered as a cantilever beam fixed on the rigid hub with high rotating speed, and the crack is deemed to be open and close continuously in a trigonometric function way with the blade vibration. It is verified by the comparison with a finite element-based contact crack model and bilinear model that the proposed NRCBM can well capture the dynamic characteristics of the rotating blade with breathing crack. The dynamic behavior of rotating cracked blade is then investigated with NRCBM, and the nonlinear damage indicator (NDI) is introduced to characterize the nonlinearity caused by blade crack. The results show that NDI is a distinguishable indicator for the severity level estimation of the crack in rotating blade. It is found that severe crack (i.e., a closer crack position to blade root as well as larger crack depth) is expected to heavily reduce the stiffness of rotating blade and apparently result in a lower resonant frequency. Meanwhile, the super-harmonic resonances are verified to be distinguishable indicators for diagnosing the crack existence, and the third-order super-harmonic resonances can serve as an indicator for the presence of severe crack since it only distinctly appears when the crack is severe.

关键词: rotating blade     breathing crack     nonlinear vibration     nonlinear damage indicator    

标题 作者 时间 类型 操作

Anthocyanins/chitosan films doped by nano zinc oxide for active and intelligent packaging: comparison of anthocyanins source from purple tomato or black wolfberry

期刊论文

A cellphone-based colorimetric multi-channel sensor for water environmental monitoring

期刊论文

Label-free colorimetric nanosensor with improved sensitivity for Pb

Abdul Ghaffar Memon, Xiaohong Zhou, Yunpeng Xing, Ruoyu Wang, Lanhua Liu, Mohsin Khan, Miao He

期刊论文

Midline2 is overexpressed and a prognostic indicator in human breast cancer and promotes breast cancer

期刊论文

Biomineralization-inspired copper-cystine nanoleaves capable of laccase-like catalysis for the colorimetric

Miao Guan, Mengfan Wang, Wei Qi, Rongxin Su, Zhimin He

期刊论文

Screening of indicator pharmaceuticals and personal care products in landfill leachates: a case study

期刊论文

Investigating the role of exiting vehicles and turn indicator usage in gap acceptance at single-lane

Nathan P. BELZ

期刊论文

Modeling effects of a tidal barrage on water quality indicator distribution in the Severn Estuary

Guanghai GAO, Roger A. FALCONER, Binliang LIN

期刊论文

A novel flavonol-based colorimetric and turn-on fluorescent probe for rapid determination of hydrazine

期刊论文

Water environment security indicator system for urban water management

Tian HAO, Pengfei DU, Yun GAO

期刊论文

China’s Agriculture Green Development: from Concept to Actions

期刊论文

A simple, azulene-based colorimetric probe for the detection of nitrite in water

Lloyd C. Murfin, Carlos M. López-Alled, Adam C. Sedgwick, Jannis Wenk, Tony D. James, Simon E. Lewis

期刊论文

Midline2 is overexpressed and a prognostic indicator in human breast cancer and promotes breast cancer

null

期刊论文

A review of measurement methods for peracetic acid (PAA)

Chen Cheng, Haodong Li, Jinling Wang, Hualin Wang, Xuejing Yang

期刊论文

Nonlinear dynamic behavior of rotating blade with breathing crack

Laihao YANG, Zhu MAO, Shuming WU, Xuefeng CHEN, Ruqiang YAN

期刊论文